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Hydrogen sulfide
Hydrogen-sulfide-2D-dimensions.svg
Hydrogen-sulfide-3D-balls.png
Hydrogen-sulfide-3D-vdW.svg
Other names
  • Dihydrogen monosulfide
  • Dihydrogen sulfide
  • Sewer gas
  • Sulfane
  • Sulfurated hydrogen
  • Sulfureted hydrogen
  • Sulfuretted hydrogen
  • Sulfur hydride
  • Hydrosulfuric acid
  • Hydrothionic acid
  • Thiohydroxic acid
  • Sulfhydric acid
Identifiers
CAS number7783-06-4
PubChem402
EC number231-977-3
KEGGC00283
MeSHHydrogen+sulfide
ChEBICHEBI:16136
RTECS numberMX1225000
SMILES[H]S[H]
Beilstein Reference3535004
Gmelin Reference303
3DMetB01206
Properties
Molecular formulaH2S
Molar mass34.08 g mol-1
AppearanceColorless gas
OdorRotten eggs
Density1.363 g dm−3
Melting point

−82 °C, 191 K, -116 °F

Boiling point
Solubility in water4 g dm−3 (at 20 °C)
Vapor pressure1740 kPa (at 21 °C)
Acidity (pKa)7.0
−25.5·10−6 cm3/mol
Refractive index (nD)1.000644 (0 °C)
Structure
C2v
Molecular shapeBent
Dipole moment0.97 D
Thermochemistry
Std enthalpy of
formation
ΔfHo298
−21 kJ mol−1
Standard molar
entropy
So298
206 J mol−1 K−1
Specific heat capacity, C1.003 J K−1 g−1
Hazards
EU classificationFlammable F+ Very Toxic T+ Dangerous for the Environment (Nature) N
Main hazardsFlammable and highly toxic
NFPA 704

NFPA 704.svg

4
4
0
 
R-phrasesR12, R26, R50
S-phrases(S1/2), S9, S16, S36, S38, S45, S61
Explosive limits4.3–46%
U.S. Permissible
exposure limit (PEL)
C 20 ppm; 50 ppm [10-minute maximum peak]
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Hydrogen sulfide (British English: hydrogen sulphide) is the chemical compound with the formula H2S, is a colorless, toxic, flammable gas that is responsible for the foul smell of rotten eggs and flatulence. It often results when bacteria break down organic matter if there is no oxygen. This happens in swamps, and sewers (alongside the process of anaerobic digestion). It also happens in volcanic gases, natural gas and some well waters. This is the smell that people often think to be that of sulfur. But sulfur itself does not smell.

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