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Sulfur dioxide
Sulfur-dioxide-2D.svg
Sulfur-dioxide-3D-vdW.png
160px
IUPAC nameSulfur dioxide
Other namesSulfurous anhydride

Sulfur(IV) oxide

Identifiers
CAS number7446-09-5
PubChem1119
EC number231-195-2
KEGGD05961
MeSHSulfur+dioxide
ChEBICHEBI:18422
RTECS numberWS4550000
SMILESO=S=O
Beilstein Reference3535237
Gmelin Reference1443
Properties
Molecular formulaSO2
Molar mass64.066 g mol−1
AppearanceColorless gas
OdorPungent; similar to a just-struck match
Density2.6288 kg m−3
Melting point

-72 °C, 201 K, -98 °F

Boiling point
Solubility in water94 g/L
forms sulfurous acid
Vapor pressure237.2 kPa
Acidity (pKa)1.81
Basicity (pKb)12.19
−18.2·10−6 cm3/mol
Viscosity0.403 cP (at 0 °C)
Structure
C2
Coordination
geometry
Digonal
Molecular shapeDihedral
Dipole moment1.62 D
Thermochemistry
Std enthalpy of
formation
ΔfHo298
−296.81 kJ mol−1
Standard molar
entropy
So298
248.223 J K−1 mol−1
Hazards
NFPA 704

NFPA 704.svg

0
3
0
 
U.S. Permissible
exposure limit (PEL)
TWA 5 ppm (13 mg/m3)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Sulfur dioxide (also sulphur dioxide) is the chemical compound with the formula SO2. It is a gas. It smells like burnt matches or rotten eggs. It can also cause suffocation. Sulfur dioxide is produced by volcanoes and in various industrial processes. It is also used to protect wine from oxygen and bacteria. It can be produced by burning sulfur. It dissolves in water to produce sulfurous acid. It can be oxidized to trioxide, which is dissolved in sulfuric acid to make more sulfuric acid. It is used to make sulfitesview more...





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